Ceria-based electrolytes prepared by solution combustion synthesis:The role of fuel on the materials properties
Carregando...
Data
2016
Data de publicação:
Autores IPEN
Orientador
Título da Revista
ISSN da Revista
Título do Volume
É parte de
É parte de
É parte de
Applied Catalysis B: Environmental
ODS
Exportar
Resumo
Ce0.8Sm0.2O2-x, powders were synthesized by solution combustion synthesis using citric acid, cellulose and sucrose as single, or intimately mixed, fuels. The powders were characterized by X-ray diffraction, transmission electron microscopy, X-ray photoelectron spectroscopy, N-2 sorption at -196 degrees C, H-2-temperature programmed reduction and thermogravimetric analyses. Textural properties of the powders were shaped by the peculiar employed fuel. The study of reducibility revealed that oxygen vacancies formation is mainly influenced by both parameters, specific surface area and total pore volume. The different tendency toward reduction played a key role in sintering under reducing atmosphere (4% H-2/Ar), and Ce0.8Sm0.2O2-x prepared with sucrose showed, at scanning electron microscopy images, the highest average grain size. Impedance spectroscopy experiments in air disclosed different grain boundary resistances on the basis of synthesis fuel employed and, in particular, Ce0.8Sm0.2O2-x, prepared with sucrose exhibited the best electrical performance. Solution combustion synthesis thereby was able to tailor the morphological and reduction properties of Ce0.8Sm0.2O2-x powders affecting even the microstructure of sintered pellet.
Como referenciar
ALIEOTTA, C.; LIOTTA, L.F.; PAROLA, V. la; MARTORANA, A.; MUCCILLO, E.N.S.; MUCCILLO, R. Ceria-based electrolytes prepared by solution combustion synthesis:The role of fuel on the materials properties. Applied Catalysis B: Environmental, v. 197, p. 14-22, 2016. DOI: 10.1016/j.apcatb.2016.02.044. Disponível em: http://repositorio.ipen.br/handle/123456789/26849. Acesso em: 25 Apr 2024.
Esta referência é gerada automaticamente de acordo com as normas do estilo IPEN/SP (ABNT NBR 6023) e recomenda-se uma verificação final e ajustes caso necessário.