PEREIRA, LUCIANO F.D.FERREIRA, WANDERSON L.GONÇALVES, VITOR C.SCALISE, LEVYGENEZINI, FREDERICO A.CORREA, EDUARDO L.SAXENA, RAJENDRA N.CARBONARI, ARTUR W.2020-06-182020-06-18PEREIRA, LUCIANO F.D.; FERREIRA, WANDERSON L.; GONÇALVES, VITOR C.; SCALISE, LEVY; GENEZINI, FREDERICO A.; CORREA, EDUARDO L.; SAXENA, RAJENDRA N.; CARBONARI, ARTUR W. Hyperfine interactions in Gd2Ti2O7 pyrochlore: ab initio calculations. In: INTERNATIONAL CONFERENCE ON HYPERFINE INTERACTIONS AND THEIR APPLICATIONS, February 10-15, 2019, Goa, India. <b>Abstract...</b> Mumbai, India: Tata Institute of Fundamental Research, 2019. p. 87-87. Disponível em: http://repositorio.ipen.br/handle/123456789/31314.http://repositorio.ipen.br/handle/123456789/31314The cubic pyrochlore structure of the RE2Ti2O7 (R= rare earth) form is highly geometrically frustrated antiferromagnets and Gd2Ti2O7 is particularly interesting due to the fact gadolinium has a large magnetic moment and its orbital momentum is zero. Up to nowadays, a few investigations of the local structure on Gd2Ti2O7 using hyperfine interactions techniques were made. Namely, the magnetic hyperfine interaction at Gd previously reported from Mossbauer effect spectroscopy with 155Gd [1] and perturbed angular correlation (PAC) have used to reach electric field gradient at 111mCd and 111In probe nuclei [2]. However, these studies are lacking in interpretation, so first principles calculations may led to the elucidation of the electronic structure at the specific crystalline site. Then, Gd2Ti2O7 single and doped-Cd cell simulations have performed with full potential linearized augmented plane waves methods and generalized gradient approximation from Perdew-Burke-Ernzerhorf within the WIEN2k code. Electric field gradient and magnetic hyperfine components were evaluated.87-87openAccessResumo de eventos científicos0000-0002-4499-59490000-0003-3023-17180000-0002-6318-6805https://orcid.org/0000-0002-4499-5949https://orcid.org/0000-0002-6318-6805