GARCIA, LUIS M.S.ZAMBIAZI, PRISCILLA J.CHAIR, KHAOULADOAN, TUAN D.RAMOS, ANDREZZA S.NANDENHA, JULIOSOUZA, RODRIGO F.B. deOTUBO, LARISSADUONG, ADAMNETO, ALMIR O.2022-11-302022-11-302022GARCIA, LUIS M.S.; ZAMBIAZI, PRISCILLA J.; CHAIR, KHAOULA; DOAN, TUAN D.; RAMOS, ANDREZZA S.; NANDENHA, JULIO; SOUZA, RODRIGO F.B. de; OTUBO, LARISSA; DUONG, ADAM; NETO, ALMIR O. cis-[6-(pyridin-2-yl)-1,3,5-triazine-2,4-diamine](dichloride) palladium(II)-based electrolyte membrane reactors for partial oxidation methane to methanol. <b>ACS Omega</b>, v. 7, n. 28, p. 24249-24255, 2022. DOI: <a href="https://dx.doi.org/10.1021/acsomega.2c01463">10.1021/acsomega.2c01463</a>. Disponível em: http://repositorio.ipen.br/handle/123456789/33361.2470-1343http://repositorio.ipen.br/handle/123456789/33361Methane is an abundant resource and the main constituent of natural gas. It can be converted into higher value-added products and as a subproduct of electricity co-generation. The application of polymer electrolyte reactors for the partial oxidation of methane to methanol to co-generate power and chemical products is a topic of great interest for gas and petroleum industries, especially with the use of materials with a lower amount of metals, such as palladium complex. In this study, we investigate the ideal relationship between cis-[6-(pyridin-2-yl)-1,3,5-triazine-2,4-diamine(dichloride)palladium(II)] (Pd-complex) nanostructure and carbon to obtain a stable, conductive, and functional reagent diffusion electrode. The physical and structural properties of the material were analyzed by Fourier transform infrared (FT-IR) and Raman spectroscopies, transmission electron microscopy (TEM), and X-ray powder diffraction (XRD) techniques. The electrocatalytic activity studies revealed that the most active proportion was 20% of Pd-complex supported on carbon (m/m), which was measured with lower values of open-circuit and power density but with higher efficiency in methanol production with reaction rates of r = 4.2 mol L–1·h–1 at 0.05 V.24249-24255openAccesselectrolytesfuel cellsmembranesmethaneoxidationelectrocatalystsArtigo de periódico28710.1021/acsomega.2c014630000-0001-8745-3421https://orcid.org/0000-0002-9287-6071https://orcid.org/0000-0002-6078-229X61.571.5