RODRIGO FERNANDO BRAMBILLA DE SOUZA

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  • Artigo IPEN-doc 20283
    Synthesis of hydroquinone with co-generation of electricity from phenol aqueous solution in a proton exchange membrane fuel cell reactor
    2015 - BUZZO, G.S.; RODRIGUES, A.C.B.; SOUZA, R.F.B. de; SILVA, J.C.M.; BASTOS, E.L.; SPINACE, E.V.; NETO, A.O.; ASSUMPCAO, M.H.M.T.
    In a proton exchange membrane fuel cell (PEMFC) an aqueous solution containing 100 mg L−1 of phenol was oxidized at the anode using PtRu/C as catalyst while oxygen gas was reduced at cathode using Pt/C as catalyst. The use of a fuel cell as a flow reactor allowed obtaining hydroquinone, an important compound much used in medicine and cosmetic industry, as product with the co-generation of electricity. A conversion of 20% of phenol with the formation of 16 mg L−1 of hydroquinone (80% of selectivity) was observed after 240 min of fuel cell operation at 80 °C.