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  • Artigo IPEN-doc 28657
    Reducing the risk for the biota by reusing a NORM residue
    2022 - NISTI, M.B.; CAVALCANTE, F.; SAUEIA, C.H.R.; MAZZILLI, B.P.
    All biota is exposed to natural radiation, the soil being the major source of radionuclides. Phosphogypsum (PG) is classified as a NORM residue of the phosphate fertilizer industry, often used in agriculture, as a soil conditioner. This residue is stored in stacks by the phosphate industries, potentially posing environmental risks. The aim of this study is to compare the risk for the terrestrial and aquatic biota arising from the storage of PG residue in the environment with that arising from its reuse as soil amendment. For this purpose, typical Brazilian soils amended with PG and PG itself were leached with distilled water. The concentration of natural radionuclides in the soil samples were used to evaluate the risk for terrestrial and aquatic biota, using the ERICA Tool. The results for terrestrial biota exposed to soils amended with phosphogypsum showed a risk reduction of about 85%, when compared to the exposure arising from phosphogypsum stacks. Considering the aquatic biota, the results showed a risk reduction of about 46% when comparing to radionuclide concentrations in leachates from phosphogypsum and from the soils amended with phosphogypsum. A new risk reduction assessment was performed to determine exclusively the contribution of the application of PG to the soil using the soil without PG, the risk reduction for terrestrial biota was of 99% and aquatic biota was a 74% reduction. Finally, it can be concluded that the addition of phosphogypsum in soils reduces the risk quotient related to the exposure of terrestrial and aquatic biota, showing that this is a safe practice.
  • Artigo IPEN-doc 27192
    Optimization of the gamma-ray spectrometry counting time based on uncertainties of radionuclides concentration in samples
    2020 - NISTI, M.B.; MADUAR, M.F.; SAUEIA, C.H.R.; CAVALCANTE, F.; MAZZILLI, B.P.
    This paper aims to propose an easy and fast method of optimization of the gamma-ray spectrometry counting time in determining natural radionuclides (210Pb, 212Pb, 214Pb, 212Bi, 214Bi and 228Ac) in order to minimize uncertainties in the concentration. The samples were measured by gamma-ray spectrometry with a hyper-pure germanium detector Canberra, 25% relative efficiency, effective resolution of 1.9 keV on the 1332.5 keV 60Co with associated electronics and coupled to a microcomputer. Multichannel Maestro A65-I model was used for spectrum acquisition and peak net area determination, and WinnerGamma/Interwinner 6.01 software was used for gamma-ray spectra analysis and to calculate the concentrations and associated uncertainties. The counting times used were 86,000 s and 150,000 s.