MARIANA DO NASCIMENTO SARTORI

MARIANA DO NASCIMENTO SARTORI

Página do item completo

Resultados de Busca

Agora exibindo 1 - 5 de 5

Reuse of textile waste with nano reinforcement for the development of materials incorporated with nanocomposites
2023 - SARTORI, MARIANA do N.; CASTRO, DIONE P. de; SILVA, LEONARDO G. de A. e
The use of plastics in Brazil and the world has shown a growing demand due to their qualities, ease of obtaining, and low cost, and, consequently, produces an increase of these plastics in solid urban waste. The destination of these materials, especially in Brazil, is summarized in sending to landfills, incineration and, mechanical and chemical recycling. This study evaluates the possibility of using polyamide textile waste with elastane discarded by the textile industry, as reinforcement for the development of a polymer-clay composite, on a nanometric scale, and develop a recycling route for these materials. In that, the nanocomposite technology adds value to this material. This work used polyamides from textile waste of the industry. These materials were first processed in a compacting machine. Afterward the composites with 1, 2, and 3% in mass of Verde Clara clay/polyamide were prepared in a double screw extruder. The composites were characterized by techniques of X-ray diffraction (XRD), tensile, flexural, impact tests and thermogravimetric analysis (TGA). Results obtained were compared with the properties of the standard samples. As a conclusion of this study, it can be stated that the polyamide textile scraps with elastane can be reused forming nanocomposites with Verde Clara clay. Verde Clara clay in the proportion of 1% already confers gains in the properties of these nanocomposites.
The incorporation of the Light Green clay in the textile polyamide residues
2021 - SARTORI, M.N.; CASTRO, D.P.; VALENZUELA-DIAZ, F.R.; SILVA, L.G.A.
The aim of this work is to evaluate the possibility to use textile residues of polyamide with elastane that are discarded by the industry as a matrix of a new polymer-clay composite material, evaluated on a manometric scale, and to propose a way of recycling for these materials. At the same time, with nanocomposite technology, value is added to this material. In this work, polyamide of textile residues from industrywas used. These materials were first processed in a compacter machine. Composites at 1, 2, and 3% by weight of Light Green clay/polyamide were prepared by double screw extrusion. The properties of the composite were characterized by X-ray diffraction (XRD), tensile, flexural, impact tests, and thermogravimetric analysis (TGA). Results obtained were compared with the neat textile polyamide properties. It was concluded that it is feasible to recycle the textile residues of polyamide, and that the addition of clay, at the doses studied in this work, could lead to the obtaining of composite materials with better mechanical than untreated ones.
Effects of gamma radiation on the properties of the thermoplastic starch/poly (butylene adipate-co-terephthalate) blends
2019 - CASTRO, DIONE P. de; SARTORI, MARIANA do N.; SILVA, LEONARDO G. de A. e
The development of blends made from matrices of synthetic biodegradable polymers, and natural additives, are considered less environmentally aggressive materials. This work aimed to study the effects of gamma radiation on the properties of the thermoplastic starch (TPS)/poly(butylene adipateco- terephthalate) (PBAT). In this work, blends of TPS/PBAT were prepared with glycerol, castor oil and TWEEN® 80, which were prepared by extrusion and then subjected to the radiation process and characterized by thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), X-ray diffraction (XRD) and scanning electron microscopy (SEM). The results demonstrated increased thermal degradation for the F2 (composed by OM) and F3 (composed by OM and TWEEN® 80) regarding F0 (composed by glycerol) e F1 (composed by glycerol and TWEEN® 80) blends. A good blend component chemical interaction and partial miscibility for the blends F0 and F1 was observed and compared to the others. However, F2 and F3 blends did not present co-continuous phases; being that the XRD curve patterns were not altered by the gamma radiation. The tests performed demonstrated that the irradiated and non-irradiated samples did not have their properties significantly altered. Thus, it was concluded that it is feasible to replace castor oi l with glycerol in TPS/PBAT blends.
Reaproveitamento de aparas têxteis de poliamida 6 e poliamida 66 com elastano
2018 - SARTORI, M.N.; SILVA, L.G.A.; CASTRO, D.P.
O Brasil é um dos principais produtores do setor têxtil no mundo, gerando milhões de empregos diretos e indiretos. Contudo, tal atividade cria diversos problemas ao meio ambiente como, por exemplo, a geração de resíduos sólidos proveniente dos processos industriais, confeccionistas e também do pós-consumo. Muitas vezes estes resíduos são descartados de modo displicente em aterros sanitários contribuindo para o depósito de resíduos no ambiente. Neste trabalho foram utilizadas aparas têxteis de poliamida 6 e poliamida 66 com elastano que são descartadas pela indústria. Esses materiais foram processados inicialmente em uma máquina compactadora para redução de volume. Posteriormente, pelo processo de extrusão foram obtidos grânulos e por injeção foram preparados os corpos de prova os quais foram submetidos aos ensaios mecânicos de tração, flexão e impacto. Os resultados encontrados revelaram que tanto as aparas de poliamida 6 como as aparas de poliamida 66 com elastano são processáveis e apresentaram características viáveis para utilização na indústria em diferentes segmentos.
Efeito da radiação ionizante em blendas de pbat/amido plastificados com glicerol e óleo de mamona
2018 - CASTRO, D.P.; SARTORI, M.N.; SILVA, L.G.A.
Diversas alternativas têm sido buscadas para minimizar o impacto ambiental causado pelos polímeros convencionais. Uma importante alternativa é o uso de polímeros biodegradáveis; no entanto, em razão do seu alto custo quando comparados com polímeros convencionais, surge a necessidade de desenvolver misturas poliméricas biodegradáveis utilizando aditivos naturais degradáveis, tal como o amido modificado. A utilização de polímeros biodegradáveis tem mostrado ser uma alternativa viável ao uso dos materiais derivados das poliolefinas, principalmente em embalagens, pelo fato de poderem ser compostados e biodegradados após o seu descarte. O desenvolvimento de blendas poliméricas fabricadas com matrizes de polímeros biodegradáveis sintéticos, e aditivos naturais, são considerados materiais menos agressivos ao meio ambiente; os quais podem ser degradados pela ação de microorganismos ou enzimas. Neste trabalho, foram preparadas blendas de amido termoplástico (TPS) com PBAT, glicerol, óleo de mamona e TWEEN® 80, as quais, foram preparadas por extrusão, e posteriormente submetidas ao processo de radiação e caracterizadas por análises térmicas, mecânicas e morfológicas. Os resultados mostraram uma boa interação entre os componentes das blendas e sua miscibilidade, tanto irradiadas quanto não irradiadas.