Structural evaluation of mechanically alloyed W-50at%C powders

dc.contributor.authorSILVA, GUSTAVO S. de A. e
dc.contributor.authorLEAL NETO, RICARDO M.
dc.contributor.authorHENRIQUES, VINICIUS A.R.
dc.contributor.authorCAIRO, CARLOS A.A.
dc.contributor.authorRAMOS, ALFEU S.
dc.coverageInternacionalpt_BR
dc.date.accessioned2017-10-17T16:25:40Z
dc.date.available2017-10-17T16:25:40Z
dc.date.issued2017pt_BR
dc.description.abstractTungsten carbide is potentially attractive for development of catalysts and widely used for fabrication of cutting tools due to its high hardness and wear resistance while the ball milling can improve the mechanical properties from the metastable structures and nanomaterials. The aim of this work was to evaluate the phase transformations during milling of the W-50at%C elemental powder mixture under argon atmosphere in a planetary P-5 ball mill using WC-Co balls (10 mm diameter) and vials (225 mL), 200 rpm, and a ball-to-powder weight ratio of 10:1. Samples were collected into the vial after different times: 20, 60, 300 and 600 min. The as-milled W-50at%C powders were characterized by X-ray diffraction (XRD). Only peaks of W were identified in W-50at%C powders milled up to 600 min, which were broadened and moved to the direction of smaller diffraction angle. In addition, the lattice parameter and cell volume of W were reduced during ball milling of W-50at%C powders, indicating that the C atoms dissolved into the W lattice in order to form metastable structures. Carbon atoms were interstitially dissolved into the W lattice during the initial milling times, and its preferential substitutional dissolution was identified for longer times due to the larger amounts of crystallographic defects during ball milling.pt_BR
dc.format.extent9-12pt_BR
dc.identifier.citationSILVA, GUSTAVO S. de A. e; LEAL NETO, RICARDO M.; HENRIQUES, VINICIUS A.R.; CAIRO, CARLOS A.A.; RAMOS, ALFEU S. Structural evaluation of mechanically alloyed W-50at%C powders. <b>Materials Science Forum</b>, v. 899, p. 9-12, 2017. DOI: <a href="https://dx.doi.org/10.4028/www.scientific.net/MSF.899.9">10.4028/www.scientific.net/MSF.899.9</a>. Disponível em: http://repositorio.ipen.br/handle/123456789/27918.
dc.identifier.doi10.4028/www.scientific.net/MSF.899.9pt_BR
dc.identifier.issn1662-9752pt_BR
dc.identifier.orcidhttps://orcid.org/0000-0001-5104-7392
dc.identifier.percentilfien
dc.identifier.urihttp://repositorio.ipen.br/handle/123456789/27918
dc.identifier.vol899pt_BR
dc.relation.ispartofMaterials Science Forumpt_BR
dc.rightsopenAccesspt_BR
dc.subjecttungsten carbides
dc.subjectwear resistance
dc.subjectceramics
dc.subjectmechanical properties
dc.subjectmetallurgical effects
dc.subjectalloys
dc.titleStructural evaluation of mechanically alloyed W-50at%C powderspt_BR
dc.typeArtigo de periódicopt_BR
dspace.entity.typePublication
ipen.autorRICARDO MENDES LEAL NETO
ipen.codigoautor520
ipen.contributor.ipenauthorRICARDO MENDES LEAL NETO
ipen.date.recebimento17-10pt_BR
ipen.identifier.fiSem F.I.pt_BR
ipen.identifier.ipendoc23230pt_BR
ipen.type.genreArtigo
relation.isAuthorOfPublicationb5e83d03-1f9c-4e57-8e02-628a903c95f8
relation.isAuthorOfPublication.latestForDiscoveryb5e83d03-1f9c-4e57-8e02-628a903c95f8
sigepi.autor.atividadeLEAL NETO, RICARDO M.:520:730:Npt_BR
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