Selecting plasmonic nanoshells for colorimetric sensors
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2023
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Journal of the Optical Society of America B
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In this work, the use of gold and silver nanoshells was evaluated as a starting point for the establishment of colorimetric sensor platforms. The sensitivity and linearity of the nanoplatforms (SiO2 core–metallic shell nanoparticles)
were assessed under the influence of the nanoshell configuration, color space, and light source illuminant. A computational procedure for selecting high-performance plasmonic colorimetric sensor platforms is described. The
evaluation methodology involves considering five different color spaces and 15 different color components. By
exploring crucial figures of merit for sensing, the performance of the plasmonic nanoplatforms was evaluated,
exploring Mie theory. We determined that gold nanoshells are highly efficient on colorimetric sensing, while silver
nanoshells are a better choice for spectroscopic sensors. Plasmonic nanoplatforms based on nanoshells with 10 nm
SiO2 core radii and 5 nm thick Au shells presented sensitivity values up to 4.70 RIU−1
, considering the hue angle
of the HSV color space. Color variation of up to 40% was observed, due to the adsorption of a 10 nm thick molecular layer on the gold nanoshell surface. In the search for advances in colorimetric biosensors, the optimization
approach used in this work can be extended to different nanostructures.
Como referenciar
BALTAR, RAPHAEL M.S.M.; FAROOQ, SAJID; ARAUJO, RENATO E. de. Selecting plasmonic nanoshells for colorimetric sensors. Journal of the Optical Society of America B, v. 40, n. 4, p. C40-C47, 2023. DOI: 10.1364/JOSAB.479446. Disponível em: http://repositorio.ipen.br/handle/123456789/34082. Acesso em: 13 May 2024.
Esta referência é gerada automaticamente de acordo com as normas do estilo IPEN/SP (ABNT NBR 6023) e recomenda-se uma verificação final e ajustes caso necessário.