LARISSA OLIVEIRA BERBEL

LARISSA OLIVEIRA BERBEL

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Corrosion mechanism of Ti-6Al-4V morse taper dental implants connected to 316 L stainless steel prosthetic abutment
2022 - BERBEL, LARISSA O.; VIVEIROS, BARBARA V.G. de; MICELLI, ANA L.P.; NIGRO, FREDERICO; ROSSI, JESUALDO L.; COSTA, ISOLDA
The aim of this work was to investigate the effect of galvanic coupling between stainless steel AISI 316 L abutment type Morse taper and implant made of ASTM F1108–14 Ti-6Al-4V alloy. The assembly of the two alloys was carried out using mechanical imbrication by means of successive strikes at 0.05 J force onto the abutment inserted in the implant along the centerline. Corrosion attack at the interface of the alloys was evaluated according to the number of strikes used for joining the parts. Corrosion resistance was evaluated for the samples by open circuit potential measurements as function of time and scanning vibrating electrode technique (SVET) and scanning ion selective electrode technique (SIET) in phosphate buffer solution with pH adjusted to 3.0, and into which hydrogen peroxide was added to simulate tissue inflammatory conditions. Samples were evaluated at the cross and longitudinal sections. Results indicated that the number of strikes used in assembling affected corrosion susceptibility. The lowest amount of corrosion products was associated to the highest number of strikes used. The corrosion resistance was related to the characteristics of the crevice between the implant and the abutment.
Niobium- and titanium-based coating for the protection of carbon steel SAE 1020 against corrosion
2022 - HELLEIS, RODRIGO; MAIA, GUILHERME A.R.; CASTRO, ERYZA G. de; BERBEL, LARISSA O.; COSTA, ISOLDA; BANCZEK, EVERSON do P.
Purpose: The purpose of this paper is to evaluate the protection against corrosion of carbon steel SAE 1020 promoted by a niobium- and titanium-based coating produced from a resin obtained by the Pechini method. Design/methodology/approach: A resin was prepared with ammonium niobium oxalate as niobium precursor and K2TiF6 as titanium precursor. Carbon Steel SAE 1020 plates were dip coated in the resin and calcinated for 1 h at 600 ºC. Scanning electron microscopy, energy dispersive spectroscopy and X-ray diffraction were used to characterize the coating morphologically and structurally. Open circuit potential, electrochemical impedance spectroscopy, anodic potentiodynamic polarization and scanning vibrating electrode technique were used to evaluate the corrosion protection of the coating. Findings: The electrochemical analyses evidence slight protection against corrosion of the coating by itself; however, the needle-like crystal structure obtained may potentially provide a good anchorage site, suggesting the coating could be used as a pretreatment that may present similar application to phosphating processes, generating lower environmental impacts. Originality/value: Due to increasingly restrictive environmental laws, new environmentally friendlier surface treatments must be researched. This paper approaches this matter using a combination of niobium- and titanium-based coating, produced by a cleaner process, the Pechini method.
The corrosion behavior on AA2050-T84 and AA7050-T7451 welded and non-welded by FSW
2021 - VIVEIROS, BARBARA V.G. de; BERBEL, LARISSA O.; DONATUS, UYIME; COSTA, ISOLDA
In this work, the corrosion resistance of the AA2050-T84 and AA7050-T7451 alloys welded by FSW and non-welded was investigated using chloride solutions. The corrosion resistance, microstructure and microhardness were studied. Microhardness measurements at the cross section and at the top surface of the weld identified significant differences between the various zones resulting from FSW. Characterization of the corrosion resistance was carried out by electrochemical and immersion tests. Localized electrochemical techniques were used in this work, specifically scanning vibrating electrode technique (SVET) and scanning ion-selective electrode technique (SIET). The results showed that the most electrochemically active zone at of the welded alloys was the thermomechanically affected zone (TMAZ). This zone corresponds to the transition between the two alloys. In the top surface of the welded alloys, besides the TMAZ, the heat affected zone (HAZ) was also highly active corresponding to the transition between zones of the AA7050. This was due to the formation of hardening precipitates in the HAZ of the AA7050. In the cross-section, the high activity related to the TMAZ was due to the galvanic coupling between the two alloys where the AA7050 alloy acted as anodic zones, and the AA2050, as the cathodic ones. When the two alloys, AA2050 and AA7050, were exposed separately to 0.005 mol.L-1 NaCl or 3.5 (wt%) NaCl solutions, the AA2050 alloy showed higher electrochemical activity compared to the AA7050 alloy which was due to the higher content of active micrometric precipitates in the AA2050 alloy relatively to the AA7050. However, when the alloys were coupled, the AA2050 was cathodically protected by the AA7050 alloy.
Effect of pulsed and spray multipass MAG welding on the corrosion resistance of 316L stainless steel
2021 - SILVA, JEFFERSON; REIS, SUELLEN; MAIA, ELOA L.; TERADA, MAYSA; BUGARIN, ALINE; BERBEL, LARISSA; ANDRADE, RAYANNE A.; GUILHERME, LUIS H.; COSTA, ISOLDA
In this study, the corrosion resistance of the ASTM A-240 TP 316L stainless steel submitted to a multipass metal active gas (MAG) welding was investigated. The stainless steel was MAG welded in two modes of metal transfer: pulsed and spray with protective gas (98% Argon and 2% Oxygen). The microstructure and corrosion resistance of base metal (BM) and fusion-zone (FZ) were characterized by scanning electron microscopy (SEM), ferritescope test, and anodic polarization tests. All zones were passive in the test solution (NaCl 1.0 mol L-1) followed by passive film breakdown with a potential increase. The BM showed a higher tendency to film breakdown comparatively to the FZ. The FZ in the spray process presented a passive film with higher breakdown resistance than the pulsed FZ.
Corrosion of dental implants made of Ti-6Al-4V connected to 316L SS in agressive environment
2021 - BERBEL, LARISSA O.; VIVEIROS, BARBARA V.G. de; MICELLI, ANA L.; NIGRO, FREDERICO; ROSSI, JESUALDO L.; COSTA, ISOLDA
Implants made of dissimilar alloys, such as Ti-6Al-4V, connected to abutment of stainless steel (SS), are being considered for application as dental implants leading to galvanic corrosion. Body fluids are corrosive electrolytes that contain aggressive ions, such as chlorides, leading to localized attack at weak points of the passive film on materials used for implants fabrication. Another reason of apprehension concerning corrosion is the method of joining the different materials. This might lead to small gaps between the two materials and promote crevice conditions that stimulate localized corrosion. In this study, the corrosion resistance of a Morse taper dental implants made of Ti-6Al-4V alloy in contact to a prosthetic abutment of 316L, with the two parts joined by mechanical forces consisting of strikes, using different numbers of strikes (3, 5 and 7), was studied. The study was carried out by SVET technique in phosphate buffer solution (PBS) with an addition of H2O2 and pH adjust to 3 to simulate inflammatory conditions. The results showed high electrochemical activity at the interface between the two alloys. SVET maps showed that the Ti alloy acted as anode whereas the 316L SS as cathode. At the interface of the dissimilar alloys, large amounts of corrosion products accumulated showing the effect of the galvanic corrosion. This was mainly observed for the samples with 3 strikes for joining both alloys. The electrochemical activity was the lowest for the dental implant mounted with 5 strikes. SVET maps and SEM images showed a strong effect of crevice corrosion for the implants joined by lowest number of strikes among the testes.
Comparing the corrosion behaviour of AA2050 and AA7050 aluminium alloys by scanning vibrating electrode and scanning ion-selective electrode techniques
2022 - VIVEIROS, BARBARA V.G. de; DONATUS, UYIME; ALENCAR, MAICON C. de; BERBEL, LARISSA O.; COSTA, ISOLDA
The susceptibility to localised corrosion of the high strength alloys, AA2050-T84 and AA7050-T7451, used in the aerospace industry, was investigated in this study by localised electrochemical techniques, specifically, scanning vibrating electrode technique (SVET) and scanning ion-selective electrode technique (SIET), in 0.005 mol L−1 NaCl solution. The study was initially carried out using both alloys individually and then, coupling the two alloys and evaluating the effect of galvanic coupling between them. The results revealed that the AA2050-T84, being nobler than the AA7050-T7451, presented higher corrosion current density values when tested in isolation and the depth of corrosion penetration was significantly deeper in the AA2050-T84 alloy than in the AA7050-T7451. However, galvanic coupling of the two alloys resulted in cathodic protection of the AA2050-T84 alloy and a reduction in corrosion current densities on both alloys.
Estudo do comportamento frente à corrosão da liga de magnésio AZ31 de uso em implantes temporários utilizando soluções simuladoras de fluidos corpóreos
2019 - SILVA, C.A.J.; BRAGUIN, L.N.M.; VIVEIROS, B.G.; BERBEL, L.O.; ROSSI, J.L.; COSTA, I.; SAIKI, M.
Atualmente, ligas de magnésio estão ganhando grande interesse para aplicações médicas devido a sua propriedade de degradação no corpo humano, principalmente para aplicações de interesse como stents cardiovasculares e próteses ortopédicas. Estes implantes temporários fornecem uma estabilidade mecânica necessária para o reparo e corroem completamente após o tempo de vida útil e fim do tratamento. Contudo, uma dificuldade na aplicação destes materiais na indústria de biomateriais é a corrosão antecipada e precoce à cura celular. Amostras da liga de magnésio AZ31 foram cortadas em lascas e a técnica escolhida para análise química elementar foi a Análise por Ativação com Nêutrons (NAA). Irradiações de curta e longa duração foram realizadas nas amostras juntamente com padrões sintéticos no reator IEA-R1 em um fluxo de nêutrons térmicos abaixo de 4,0x1012 n cm-2s-1. Concentrações dos elementos As, La, Mg, Mn, Na, Sb e Zn foram determinadas na liga AZ31, calculadas pelo método comparativo. Para os ensaios de corrosão, as amostras foram limpas com álcool etílico, acetona e água purificada MilliQ por agitação ultrassônica, e, em seguida foram lixadas com lixas de SiC com granulometria de #500, #800, #1200, #2000 e #4000. Testes de visualização em ágar-ágar e imersão foram realizados em solução de cloreto de sódio 0,90 % (massa), solução tampão de fosfato (PBS) e solução simuladora de fluidos corpóreos (SBF) utilizando fenolftaleína como indicador ácido-base. A observação das superfícies das amostras, antes e após exposição às soluções, foi realizada por microscopia óptica (MO) e microscopia eletrônica de varredura (MEV). A superfície também foi observada após remoção dos produtos de corrosão por desmutting e irradiação para análise quantitativa pela técnica NAA. Visualizações em gel ágarágar revelaram aumento do pH local proveniente da liberação de íons hidroxila da reação catódica e menor liberação de íons ocorreu em SBF em comparação às soluções de NaCl e PBS. As micrografias da superfície evidenciaram a formação instantânea de uma camada de produtos de corrosão após uma hora de ensaio e o desmutting revelou microcavidades caracterizadas por pites.
Estudo da resistência à corrosão do aço inoxidável austenítico ISO 5832-1 utilizado como implante ortopédico
2019 - BRAGUIN, L.N.M.; SILVA, C.A.J.; BERBEL, L.O.; COSTA, I.; SAIKI, M.
O aço inoxidável austenítico ISO 5832-1 utilizado como biomaterial é muito aplicado na área de ortopedia, especialmente na fabricação de implantes, como substituição temporária ou permanente de estruturas ósseas. Este aço apresenta biocompatibilidade, alta resistência mecânica, resistência à corrosão e baixo custo quando comparado a outros biomateriais, como ligas de titânio e de Cr-Co. O objetivo deste estudo foi avaliar a resistência à corrosão localizada do aço inoxidável ISO 5832-1 utilizado em implantes ortopédicos por ensaios eletroquímicos em duas soluções diferentes. Este estudo é de grande interesse para avaliar a corrosão dos implantes metálicos que podem prejudicar a estrutura do biomaterial e liberar produtos de corrosão nos fluidos corpóreos causando possíveis reações biológicas adversas. A determinação dos elementos químicos da composição do aço inoxidável austenítico ISO 5832- 1 foi realizada por análise por ativação com nêutrons (NAA). Para estas análises foram obtidas lascas deste material. Cerca de 50 mg de amostra foram pesadas em envelopes de polietileno e irradiados junto com padrões sintéticos de elementos. Irradiações de curta e longa duração foram realizadas no reator nuclear de pesquisa, IEA-R1, utilizando um fluxo de neutrons térmicos de cerca de 4,5 x 10^12 n cm^-2 s^-1. Para os ensaios eletroquímicos, as amostras de liga foram lixadas com lixas de SiC de granulometria #320, #500, #1200, #2000 e #4000 e polidas com pasta de diamante de 1μm. As medidas de potencial de circuito aberto e polarização potenciodinâmica catódica e anódica foram realizadas em solução de 0,90 % (massa) de NaCl e de solução simuladora de fluido corpóreo (SBF). A alta resistência à corrosão deste aço foi atribuída à formação de filme de óxido passivo que reduz a taxa de corrosão, dificultando o transporte de íons metálicos e de elétrons, que provocam a possível liberação de íons tóxicos para o corpo humano.
The corrosion resistance between AA2050-T84 and AA7050-T7451 welded by friction stir weld
2019 - VIVEIROS, BARBARA V.G. de; BERBEL, LARISSA O.; BUGARIN, ALINE F.S.; DONATUS, UYIME; COSTA, ISOLDA
Aluminum alloys of the 2XXX and 7XXX series are among the most used materials in the aerospace industry. These alloys have good mechanical, specific strength and corrosion resistance, and for the 2XXX series, further reduction in density can be achieved by lithium addition. So, in this case, it can reduce the weight of the aeroplane and fuel usage leading to the minimization of CO 2 emissions and cost savings. Aluminum alloys have poor weldability, and to use these alloys for aeroplane structures, joining is unavoidable. To make this, the industry uses rivets to join these alloys. But rivets increase the mass of aeroplanes, and to minimise this, a non-fusion (unconventional) welding technique capable of welding aluminium alloys easily was developed. This new technique is friction stir welding, which exposes the aluminum alloys to thermomechanical effects, changing the microstructure of the alloys, and resulting in different regions with different metallurgical and mechanical properties. An example of the regions is the thermomechanically affected region which experiences both plastic deformation and high temperature but without recrystallization. There is also the stir zone which is the region of recrystallized grains, the heat affected zone and the base metal (that is not affected by the welding process). The goals of this work are to analyze the corrosion resistance of the friction stir weldment of dissimilar AA2050-T84 and AA7050-T7451 alloys using electrochemical tests, characterizing the different regions of the weldment, and establishing the most susceptible region to corrosion using a sodium chloride solution.
Determinants of corrosion resistance of Ti-6Al-4V alloy dental implants in an In Vitro model of peri-implant inflammation
2019 - BERBEL, LARISSA O.; BANCZEK, EVERSON do P.; KAROUSSIS, IOANNIS K.; KOTSAKIS, GEORGIOS A.; COSTA, ISOLDA
Background Titanium (Ti) and its alloys possess high biocompatibility and corrosion resistance due to Ti ability to form a passive oxide film, i.e. TiO2, immediately after contact with oxygen. This passive layer is considered stable during function in the oral cavity, however, emerging information associate inflammatory peri-implantitis to vast increases in Ti corrosion products around diseased implants as compared to healthy ones. Thus, it is imperative to identify which factors in the peri-implant micro-environment may reduce Ti corrosion resistance. Methods The aim of this work is to simulate peri-implant inflammatory conditions in vitro to determine which factors affect corrosion susceptibility of Ti-6Al-4V dental implants. The effects of hydrogen peroxide (surrogate for reactive oxygen species, ROS, found during inflammation), albumin (a protein typical of physiological fluids), deaeration (to simulate reduced pO2 conditions during inflammation), in an acidic environment (pH 3), which is typical of inflammation condition, were investigated. Corrosion resistance of Ti-6Al-4V clinically-relevant acid etched surfaces was investigated by electrochemical techniques: Open Circuit Potential; Electrochemical Impedance Spectroscopy; and Anodic Polarization. Results Electrochemical tests confirmed that most aggressive conditions to the Ti-6Al-4V alloy were those typical of occluded cells, i.e. oxidizing conditions (H2O2), in the presence of protein and deaeration of the physiological medium. Conclusions Our results provide evidence that titanium’s corrosion resistance can be reduced by intense inflammatory conditions. This observation indicates that the micro-environment to which the implant is exposed during peri-implant inflammation is highly aggressive and may lead to TiO2 passive layer attack. Further investigation of the effect of these aggressive conditions on titanium dissolution is warranted.