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Agora exibindo 1 - 10 de 19
  • Artigo IPEN-doc 30267
    Aspects of higly microplastic contamination in the Atlantic Forest estuary
    2023 - PARRA, DUCLERC F.; GIMILIANI, GIOVANA; SANTOS, JACINETE L. dos; COTRIM, MARYCEL E.B.
    The Atlantic Forest is one of the richest regions in terms of biodiversity in the world. Originally the biome covered about 15% of the national territory. Currently, only about 12.4% (SOS MATA ATLÂNTICA, 2021) of well-preserved forest remnants remain in the country [1]. Regarding mangrove areas, in the state of São Paulo there are about 223 km², according to the Atlas of mangroves in Brazil, with about 120.5 km² of this total in Baixada Santista. Analyzes of sediments collected at Santos estuarine mangroves, in various points show a high concentration of microplastics generated from industrial processes or even anthropogenic activity. These solid particles based on (< 5 mm) are today one of the main environmental problems. The microplastics present in the sediment samples were quantified after drying and sieving amount limited of sediment. FTIR and micro-Raman spectroscopy identified filaments and fragments of microplastics (MPs) as commom polymer spectra. Also additives and herbicides were present in some MPs. All polymeric types identified (<5mm) have wide applications and demands by packaging, civil construction, automotive, electrical and electronics, and textile sectors.
  • Artigo IPEN-doc 27924
    Study of new routes for purification of fission 99Mo
    2021 - DAMASCENO, M.O.; MARQUES, F.A. da S.; DIAS, R.R.; SANTOS, J.L.; FORBICINI, C.A.L.G.O.
    99mTc is the most used medical radioisotope in the world, especially for diagnosis procedures. It is originated in the radioactive decay of 99Mo, which in turn is one of the fission products of the uranium irradiation that occurs in nuclear reactors. The chemical processing of 99Mo might be lined up in several steps according to the characteristics of the targets or the local requirements in order to separate it from other fission products. In this work, two routes of 99Mo purification, MR1 and MR2, were purposed as an alternative method to be set up in the Brazilian Multipurpose Reactor project. The MR1 route consisted by three consecutives chromatographic columns packed with strong anionic resin, Chelating resin, and aluminum oxide, respectively. The MR2 route was arranged in two chromatographic columns and a sublimation oven. The final yield for the MR1 was 84.4% and the overall time process was about 7 hours, performing the highest final 99Mo recovery efficiency, high decontamination degree and a shorter process time compared to the MR2.
  • Artigo IPEN-doc 26232
    Study of new routes for purification of fission (99)Mo
    2019 - DAMASCENO, MARCOS O.; MARQUES, FERNANDA A. da S.; DIAS, RICARDO R.; SANTOS, JACINETE L. dos; FORBICINI, CHRISTINA A.L.G. de O.
    99mTc is the most widely applied medical radioisotope in the world, especially for cancer diagnosis procedures. It is provided by 99Mo radioactive decay, which is one of the fission products of irradiated uranium by nuclear reactors. At main production centers, 99Mo chemical processing line up different steps to separate it from other fission products, depending on features of targets or local requirements. In this work, two new routes (MR1 and MR2) for 99Mo purification are presented, called MR1 and MR2, can be set up in the Brazilian Multipurpose Reactor project (RMB). In the first studied route, 99Mo purification initiated by eluting the solution through a Dowex 1x8 resin chromatography column, followed by a second step using a Chelex resin column and finally, the process was finished using an alumina column. For a second route, the first step is also performed with a Dowex 1x8 column, followed by a second separation step using alumina column, and lastly, a sublimation process was carried out in a tubular oven under programmed conditions. The final yield for the MR1 route has reached 84.4% and the overall time process about 7 hours, by contrast, MR2 route came to 75.3% in 9 hours.
  • Resumo IPEN-doc 14451
    Utilizacao de membranas liquidas suportadas (MLS) e agentes extratores da familia dos macrociclicos e das beta-dicetonas
    2007 - DINIZ, YARA L.; FELINTO, MARIA C.F. da C.; SANTOS, JACINETE L. dos
  • Resumo IPEN-doc 16281
    Transport of Eu(III) ions through a supported liquid membrane containing thenoyltrifluoroacetone
    2008 - SANTOS, J.L. dos; FELINTO, M.C.F.C.; DINIZ, Y.L.
  • Resumo IPEN-doc 15390
    Removal of U(VI) through supported liqui membranes with TBP in PTFE films
    2006 - SANTOS, JACINETE L. dos; FELINTO, MARIA C.F.C.; DINIZ, YARA L.
  • Resumo IPEN-doc 12395
    Estudo do comportamento de extracao do Eusup(3+) utilizado acetatos de calixarenos em CHClsub(3) como agentes extratores
    2007 - SANTOS, JACINETE L. dos; DINIZ, YARA L.; FELINTO, MARIA C.F.C.
  • Resumo IPEN-doc 13579
    Transporte de Eu(III) utilizando a tecnica de membrans liquido suportadas (MLS) e calixarenos como moleculas carregadoras
    2008 - SANTOS, JACINETE L. dos; DINIZ, YARA L.; FELINTO, MARIA C.F.C.
  • Resumo IPEN-doc 13571
  • Artigo IPEN-doc 19411
    Adsorption behavior of sup(99)Mo using AGI-X8 anionic resin
    2013 - SANTOS, JACINETE L. dos; YAMAURA, MITIKO; DAMASCENO, MARCOS O.; FORBICINI, CHRISTINA A.L.G.O.