Crystallographic parameters of magnetic Pr2Fe14−xCoxB-type alloys determined using anomalous x-ray diffraction with synchrotron radiation

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2017
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Journal of Magnetism and Magnetic Materials
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Anomalous x-ray synchrotron diffraction was used to determine the crystallographic parameters of PrFeCoBbased magnetic alloys. The effect of cobalt concentration on the crystallographic parameters of the magnetically hard Pr2Fe14−xCoxB phase was studied. The results indicate that addition of cobalt has a marked effect on crystal structure. Variation of the c parameter decreased twice as much as the a parameter with increase in Co content. The positions of inequivalent atoms of the magnetically hard matrix phase ϕ in the Pr-based alloys were determined using Rietveld refinement. This permitted determination of the relative distance of each inequivalent atom from its nearest neighbors. Cobalt occupied the 16k2 site and Fe had a tendency to occupy the 8j2 sites located between the Kagomé layers.

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GALEGO, E.; SERNA, M.M.; RAMANATHAN, L.V.; FARIA, R.N. Crystallographic parameters of magnetic Pr2Fe14−xCoxB-type alloys determined using anomalous x-ray diffraction with synchrotron radiation. Journal of Magnetism and Magnetic Materials, v. 424, p. 298-303, 2017. DOI: 10.1016/j.jmmm.2016.10.070. Disponível em: http://repositorio.ipen.br/handle/123456789/26909. Acesso em: 16 Mar 2025.
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