Naphthenic acid corrosion of API 5L X70 steel in aqueous/oil environment using electrochemical surface-resolved and analytical techniques

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2022
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Electrochimica Acta
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Naphthenic acid corrosion of steel is studied in crude oil/aqueous phase system at ambient temperature, using a biphasic stagnant liquid without emulsification, by means of electrochemical measurements and surface analysis. The in-situ electrochemical impedance is assigned to the processes occurring at the aqueous phase. Corrosion occurred only in the region of the aqueous phase, as crater-shaped pits that eventually coalesced, generating a nearly uniform attack in the vicinity of the oil phase. The impedance values, normalized to the aqueous region only, reveal corrosion rate increasing with the ratio of crude oil/water. Despite the localized character of the anodic oxidation, the iron naphthenate corrosion products became partitioned between the two phases. Surface-resolved electrochemical techniques in aqueous solution revealed enhanced activity of the regions pre-exposed to oil.

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SILVA, REJANE M.P.; SUFFREDINI, HUGO B.; BASTOS, IVAN N.; SANTOS, LUIS F.; SIMOES, ALDA M.P. Naphthenic acid corrosion of API 5L X70 steel in aqueous/oil environment using electrochemical surface-resolved and analytical techniques. Electrochimica Acta, v. 407, p. 1-12, 2022. DOI: 10.1016/j.electacta.2022.139900. Disponível em: http://repositorio.ipen.br/handle/123456789/32966. Acesso em: 27 Apr 2024.
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