Effect of silicon doping in HFO2 nanoparticles from an atomic view
| dc.contributor.author | SALES, TATIANE S.N. | |
| dc.contributor.author | CARBONARI, ARTUR W. | |
| dc.coverage | Internacional | pt_BR |
| dc.creator.evento | INTERNATIONAL NUCLEAR ATLANTIC CONFERENCE | pt_BR |
| dc.date.accessioned | 2018-01-08T12:00:57Z | |
| dc.date.available | 2018-01-08T12:00:57Z | |
| dc.date.evento | October 22-27, 2017 | pt_BR |
| dc.description.abstract | We have prepared the Hafnium Oxide (HfO2) nanoparticles (NPs) doped with 5% at. of silicon (Si) using the sol-gel chemical method. Nuclear quadrupole interactions at Hf sites were investigated by perturbed γ–γ angular correlations (PAC) spectroscopy using 181Ta as probe nuclei. This method is based on the hyperfine interactions between the nuclear moments of the probe nuclei with extra-nuclear magnetic fields or electric field gradients (EFGs). In the case of quadrupolar electric interactions, experimental measurements give the quadrupole frequency Q with respective distribution () as well the asymmetry parameter of of of the EFG. The hyperfine parameters were measured within the range from 200°C to 900°C. The structural and morphological characterization of the samples were carried out by X-ray diffraction and scanning electron microscopy (SEM) with electron back scattering diffraction (EBSD). PAC results show a major site fraction of probe nuclei, that was assigned to the monoclinic phase of HfO2, with approximately 60% population, which increases when the temperature of heat treatment increases. The XRD results showed a single phase with the expected monoclinic structure for the as-prepared samples indicating that Si atoms are at substitutional Hf sites. | pt_BR |
| dc.event.sigla | INAC | pt_BR |
| dc.identifier.citation | SALES, TATIANE S.N.; CARBONARI, ARTUR W. Effect of silicon doping in HFO2 nanoparticles from an atomic view. In: INTERNATIONAL NUCLEAR ATLANTIC CONFERENCE, October 22-27, 2017, Belo Horizonte, MG. <b>Proceedings...</b> Rio de Janeiro, RJ: Associação Brasileira de Energia Nuclear, 2017. Disponível em: http://repositorio.ipen.br/handle/123456789/28236. | |
| dc.identifier.orcid | https://orcid.org/0000-0002-4499-5949 | |
| dc.identifier.uri | http://repositorio.ipen.br/handle/123456789/28236 | |
| dc.local | Rio de Janeiro, RJ | pt_BR |
| dc.local.evento | Belo Horizonte, MG | pt_BR |
| dc.publisher | Associação Brasileira de Energia Nuclear | pt_BR |
| dc.rights | openAccess | pt_BR |
| dc.subject | doped materials | |
| dc.subject | hafnium oxides | |
| dc.subject | nanoparticles | |
| dc.subject | perturbed angular correlation | |
| dc.subject | quadrupoles | |
| dc.subject | silicon | |
| dc.subject | sol-gel process | |
| dc.subject | tantalum 181 | |
| dc.subject | temperature dependence | |
| dc.title | Effect of silicon doping in HFO2 nanoparticles from an atomic view | pt_BR |
| dc.type | Texto completo de evento | pt_BR |
| dspace.entity.type | Publication | |
| ipen.autor | ARTUR WILSON CARBONARI | |
| ipen.autor | TATIANE DA SILVA NASCIMENTO | |
| ipen.codigoautor | 1437 | |
| ipen.codigoautor | 9322 | |
| ipen.contributor.ipenauthor | ARTUR WILSON CARBONARI | |
| ipen.contributor.ipenauthor | TATIANE DA SILVA NASCIMENTO | |
| ipen.date.recebimento | 18-01 | pt_BR |
| ipen.event.datapadronizada | 2017 | pt_BR |
| ipen.identifier.ipendoc | 24061 | pt_BR |
| ipen.notas.internas | Proceedings | pt_BR |
| ipen.type.genre | Artigo | |
| relation.isAuthorOfPublication | 8f236231-e73c-4182-a596-d83e49cd0404 | |
| relation.isAuthorOfPublication | 24b79047-b1bf-4409-a205-0d39870c9cfd | |
| relation.isAuthorOfPublication.latestForDiscovery | 24b79047-b1bf-4409-a205-0d39870c9cfd | |
| sigepi.autor.atividade | SALES, TATIANE S.N.:9322:-1:S | pt_BR |
| sigepi.autor.atividade | CARBONARI, ARTUR W.:1437:310:N | pt_BR |