Electron beam irradiation process applied to primary and secondary recycled high density polyethylene

dc.contributor.authorCARDOSO, JESSICA R.
dc.contributor.authorMOURA, EDUARDO de
dc.contributor.authorGERALDO, AUREA B.C.
dc.coverageInternacionalpt_BR
dc.creator.eventoINTERNATIONAL NUCLEAR ATLANTIC CONFERENCEpt_BR
dc.date.accessioned2018-01-17T16:20:15Z
dc.date.available2018-01-17T16:20:15Z
dc.date.eventoOctober 22-27, 2017pt_BR
dc.description.abstractPlastic bags, packaging and furniture items are examples of plastic utilities always present in life. However, the end-of-life of plastics impacts the environment because of this ubiquity and also often their high degradation time. Recycling processes are important in this scenario because they offer many solutions to this problem. Basically, four ways are known for plastic recycling: primary recycling, which consists in re-extrusion of clean plastic scraps from a production plant; secondary recycling, that uses end-of-life products that generally are reduced in size by extrusion to obtain a more desirable shape for reprocessing (pellets and powder); tertiary recover which is related to thermo-chemical methods to produce fuels and petrochemical feedstock; and quaternary route, that is related to energy recovery and it is done in appropriate reactors. In this work, high density polyethylene (HDPE) was recovered to simulate empirically the primary and secondary recycling ways using materials which ranged from pristine to 20-fold re-extrused materials. The final 20-fold recycled thermoplastic was irradiated in an electron beam accelerator under a dose rate of 22.4 kGy/s and absorbed doses of 50 kGy and 100 kGy. The characterization of HDPE in distinct levels of recovering was performed by infrared spectroscopy (FTIR) and thermogravimetric degradation. In the HDPE recycling, degradation and crosslinking are consecutive processes; degradation is very noticeable in the 20-fold recycled product. Despite this, the 20-fold recycled product presents crosslinking after irradiation process and the post-irradiation product presents similarities in spectroscopic and thermal degradation characteristics of pristine, irradiated HDPE. These results are discussed.pt_BR
dc.event.siglaINACpt_BR
dc.identifier.citationCARDOSO, JESSICA R.; MOURA, EDUARDO de; GERALDO, AUREA B.C. Electron beam irradiation process applied to primary and secondary recycled high density polyethylene. In: INTERNATIONAL NUCLEAR ATLANTIC CONFERENCE, October 22-27, 2017, Belo Horizonte, MG. <b>Proceedings...</b> Rio de Janeiro, RJ: Associação Brasileira de Energia Nuclear, 2017. Disponível em: http://repositorio.ipen.br/handle/123456789/28351.
dc.identifier.urihttp://repositorio.ipen.br/handle/123456789/28351
dc.localRio de Janeiro, RJpt_BR
dc.local.eventoBelo Horizonte, MGpt_BR
dc.publisherAssociação Brasileira de Energia Nuclearpt_BR
dc.rightsopenAccesspt_BR
dc.subjectabsorbed radiation doses
dc.subjectcross-linking
dc.subjectdose rates
dc.subjectelectron beams
dc.subjectextrusion
dc.subjectfourier transformation
dc.subjectinfrared spectra
dc.subjectpolypropylene
dc.subjectrecycling
dc.subjectshear
dc.subjectthermal degradation
dc.titleElectron beam irradiation process applied to primary and secondary recycled high density polyethylenept_BR
dc.typeTexto completo de eventopt_BR
dspace.entity.typePublication
ipen.autorAUREA BEATRIZ CERQUEIRA GERALDO
ipen.autorEDUARDO DE MOURA
ipen.autorJESSICA RAQUEL CARDOSO
ipen.codigoautor1466
ipen.codigoautor1060
ipen.codigoautor9371
ipen.contributor.ipenauthorAUREA BEATRIZ CERQUEIRA GERALDO
ipen.contributor.ipenauthorEDUARDO DE MOURA
ipen.contributor.ipenauthorJESSICA RAQUEL CARDOSO
ipen.date.recebimento18-01pt_BR
ipen.event.datapadronizada2017pt_BR
ipen.identifier.ipendoc24186pt_BR
ipen.notas.internasProceedingspt_BR
ipen.type.genreArtigo
relation.isAuthorOfPublication825a6fc8-dbf1-471f-aeba-bedec4f0f7a3
relation.isAuthorOfPublication8c056890-8760-424b-988b-a833663503ca
relation.isAuthorOfPublication23c4b5fd-57b4-45dd-885d-2eb1ce5af8d6
relation.isAuthorOfPublication.latestForDiscovery23c4b5fd-57b4-45dd-885d-2eb1ce5af8d6
sigepi.autor.atividadeCARDOSO, JESSICA R.:9371:220:Spt_BR
sigepi.autor.atividadeMOURA, EDUARDO DE:1060:220:Npt_BR
sigepi.autor.atividadeGERALDO, AUREA B.C.:1466:220:Npt_BR
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