Ionic conductivity of Sr- and Mg-doped lanthanum gallate with La1.55Sr0.55Ga3O7+delta addition
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2018
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INTERNATIONAL CONGRESS ON CERAMICS, 7th; CONGRESSO BRASILEIRO DE CERÂMICA, 62.
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Sr- and Mg-doped lanthanum gallates are solid electrolytes with ionic conductivity higher than that of the traditional yttria-stabilized zirconia. Moreover, doped lanthanum gallates exhibit wide electrolytic domain and good chemical stability. The combination of their properties turns this compound a promising candidate for application in solid oxide fuel cells operating at intermediate temperatures (550-750°C). In this work, small amounts of La1.55Sr0.55Ga3O7+δ was added to doped lanthanum gallate and the effects of the additive on electrical properties of the base material were investigated by the impedance spectroscopy technique. The X-ray diffraction patterns of sintered specimens show the characteristic reflections of the perovskite-type phase, along with low-intensity diffraction peaks of the commonly detected impurity phases. The impedance spectroscopy diagrams reveal the high-frequency arc due to the bulk resistivity besides a strong overlap of the grain boundary arc with that of the electrode. The grain resistivity decreases for increasing amounts of La1.55Sr0.55Ga3O7+δ.
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FUJIMOTO, T.G.; MUCCILLO, E.N.S.; CARVALHO, L.A. Ionic conductivity of Sr- and Mg-doped lanthanum gallate with La1.55Sr0.55Ga3O7+delta addition. In: INTERNATIONAL CONGRESS ON CERAMICS, 7th; CONGRESSO BRASILEIRO DE CERÂMICA, 62., June 17-21, 2018, Foz do Iguaçu, PR. Abstract... p. 537-537. Disponível em: http://repositorio.ipen.br/handle/123456789/29694. Acesso em: 29 Jul 2024.
Esta referência é gerada automaticamente de acordo com as normas do estilo IPEN/SP (ABNT NBR 6023) e recomenda-se uma verificação final e ajustes caso necessário.