LARISSA OLIVEIRA BERBEL

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  • Artigo IPEN-doc 28696
    Comparing the corrosion behaviour of AA2050 and AA7050 aluminium alloys by scanning vibrating electrode and scanning ion-selective electrode techniques
    2022 - VIVEIROS, BARBARA V.G. de; DONATUS, UYIME; ALENCAR, MAICON C. de; BERBEL, LARISSA O.; COSTA, ISOLDA
    The susceptibility to localised corrosion of the high strength alloys, AA2050-T84 and AA7050-T7451, used in the aerospace industry, was investigated in this study by localised electrochemical techniques, specifically, scanning vibrating electrode technique (SVET) and scanning ion-selective electrode technique (SIET), in 0.005 mol L−1 NaCl solution. The study was initially carried out using both alloys individually and then, coupling the two alloys and evaluating the effect of galvanic coupling between them. The results revealed that the AA2050-T84, being nobler than the AA7050-T7451, presented higher corrosion current density values when tested in isolation and the depth of corrosion penetration was significantly deeper in the AA2050-T84 alloy than in the AA7050-T7451. However, galvanic coupling of the two alloys resulted in cathodic protection of the AA2050-T84 alloy and a reduction in corrosion current densities on both alloys.
  • Artigo IPEN-doc 28131
    Study of corrosion of AA 3003 aluminum in biodiesel, diesel, ethanol and gasoline media
    2020 - SOARES, M.; BERBEL, L.O.; VIEIRA, C.; OLISZESKI, D.C.S.; FURSTENBERGER, C.B.; BANCZEK, E.P.
    The contact between fuels and various metals used in vehicles make them susceptible to corrosion. Aluminum is a metal widely used in automotive components owing to its corrosion resistance as well as mechanical properties. The ABNT 14359 standard establishes a method for determining fuel corrosion; however, it is restricted to copper and fossil fuels. In this standard, corrosion is assessed qualitatively by visual comparison of patterns, which can lead to uncertain results. The methodology used in this study involves the immersion of metallic materials in fuels for a specific period of time for further analysis by scanning electron microscopy (SEM), and electrochemical analysis by electrochemical impedance spectroscopy (EIS) and anodic potentiodynamic polarization (APP). The results indicated that aluminum alloy AA 3003 is suitable for use in the production of vehicle components that will be in contact with biodiesel, diesel, ethanol, or gasoline, since no serious case of corrosion occurred.
  • Artigo IPEN-doc 24727
    Qualitative use of potentiodynamic polarization and anodic hydrogen evolution in the assessment of corrosion susceptibility in AA2198-T851 Al–Cu–Li alloy
    2018 - DONATUS, UYIME; BERBEL, LARISSA O.; COSTA, ISOLDA
    In this study, the corrosion behavior of the AA2198-T851 and its friction stir weldment was used to show the qualitative use of potentiodynamic polarization and the effect of anodic hydrogen evolution (AHE). The results showed that some details can be revealed in the anodic arm of the polarization curves of an Al alloy above the breakdown potential with changes in cell configuration and electrolytes. In addition, AHEinterferes with the measured current density in the anodic arm, which in turn can be used to assess the extent of corrosion susceptibility and changes in anodic dissolution behavior of the alloy.