ELIANA MARIA ARICO
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Artigo IPEN-doc 10488 Thermal decomposition and indirect structural determination of rare earth element picrates with the DTSO ligand2004 - MIRANDA JUNIOR, P.; SCHPECTOR, J.Z.; MATOS, J.R.; MADUAR, M.F.; ARICO, E.M.; LINARDI, M.; ZINNER, L.B.; VICENTINI, G.The complexes [Ln(pic)3(DTSO)3] (Ln=La, Lu and Y; pic=picrate; DTSO=1,3-dithiane-1-oxide) were synthesized and characterized. Indirect structural determination by far infrared spectroscopy is presented. Results from thermal decomposition of these complexes by TG/DTG and DSC techniques are reported.