Application of binary PdSb/C as an anode in a polymeric electrolyte reactor-fuel cell type for electrosynthesis of methanol from methane

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dc.contributor.authorGODOI, CAMILA M.pt_BR
dc.contributor.authorSANTOS, MONIQUE C.L.pt_BR
dc.contributor.authorNUNES, LIVIA C.pt_BR
dc.contributor.authorSILVA, ARACELI J.pt_BR
dc.contributor.authorRAMOS, ANDREZZA S.pt_BR
dc.contributor.authorSOUZA, RODRIGO F.B. dept_BR
dc.contributor.authorNETO, ALMIR O.pt_BR
dc.coverageInternacionalpt_BR
dc.date.accessioned2022-08-09T18:39:21Z
dc.date.available2022-08-09T18:39:21Z
dc.date.issued2022pt_BR
dc.description.abstractPdSb catalyst prepared in different compositions were applied as an anode in a polymeric electrolyte reactor - fuel cell type (PER-FC) to convert methane into oxygenated products and energy in mild conditions. The PER-FC polarization curves for Pd90Sb10/C presented maximum current density about 0.92 mW cm-2 about 15% higher than PdSb materials. However, the material Pd50Sb50/C showed higher reaction rate for methanol generation than the other materials occurring close to the OCV (r ~ 7 mol L-1 h-1). The qualitative analyses of PER-FC effluent by FT-IR identified products as methanol, carbonate and formate ions from the partial oxidation of methane for all materials.pt_BR
dc.description.sponsorshipCoordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)pt_BR
dc.description.sponsorshipConselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)pt_BR
dc.description.sponsorshipFundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)pt_BR
dc.description.sponsorshipIDCAPES: 88882.315566/2019pt_BR
dc.description.sponsorshipIDCNPq: 302709/2020-7pt_BR
dc.description.sponsorshipIDFAPESP: 17/11937-4; 17/11937-4pt_BR
dc.format.extent1-8pt_BR
dc.identifier.citationGODOI, CAMILA M.; SANTOS, MONIQUE C.L.; NUNES, LIVIA C.; SILVA, ARACELI J.; RAMOS, ANDREZZA S.; SOUZA, RODRIGO F.B. de; NETO, ALMIR O. Application of binary PdSb/C as an anode in a polymeric electrolyte reactor-fuel cell type for electrosynthesis of methanol from methane. <b>Materials Research</b>, v. 25, p. 1-8, 2022. DOI: <a href="https://dx.doi.org/10.1590/1980-5373-MR-2021-0542">10.1590/1980-5373-MR-2021-0542</a>. Disponível em: http://repositorio.ipen.br/handle/123456789/33193.
dc.identifier.doi10.1590/1980-5373-MR-2021-0542pt_BR
dc.identifier.issn1516-1439pt_BR
dc.identifier.orcid0000-0001-8745-3421pt_BR
dc.identifier.orcidhttps://orcid.org/0000-0002-9287-6071
dc.identifier.percentilfi19.4pt_BR
dc.identifier.percentilfiCiteScore40.5pt_BR
dc.identifier.urihttp://repositorio.ipen.br/handle/123456789/33193
dc.identifier.vol25pt_BR
dc.relation.ispartofMaterials Researchpt_BR
dc.rightsopenAccesspt_BR
dc.subjectantimony
dc.subjectcatalysts
dc.subjectcogeneration
dc.subjectcurrent density
dc.subjectelectrolytic cells
dc.subjectfourier transformation
dc.subjectfuel cells
dc.subjectmethane
dc.subjectmethanol
dc.subjectoxidation
dc.subjectpalladium
dc.titleApplication of binary PdSb/C as an anode in a polymeric electrolyte reactor-fuel cell type for electrosynthesis of methanol from methanept_BR
dc.typeArtigo de periódicopt_BR
dspace.entity.typePublication
ipen.autorLIVIA DA COSTA NUNES
ipen.autorARACELI JARDIM SILVA
ipen.autorALMIR OLIVEIRA NETO
ipen.autorRODRIGO FERNANDO BRAMBILLA DE SOUZA
ipen.autorANDREZZA DA SILVA RAMOS
ipen.autorMONIQUE CAROLINA LIMA DOS SANTOS
ipen.autorCAMILA MARINHO GODOI SANTOS
ipen.codigoautor15092
ipen.codigoautor15469
ipen.codigoautor3541
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ipen.codigoautor14128
ipen.contributor.ipenauthorLIVIA DA COSTA NUNES
ipen.contributor.ipenauthorARACELI JARDIM SILVA
ipen.contributor.ipenauthorALMIR OLIVEIRA NETO
ipen.contributor.ipenauthorRODRIGO FERNANDO BRAMBILLA DE SOUZA
ipen.contributor.ipenauthorANDREZZA DA SILVA RAMOS
ipen.contributor.ipenauthorMONIQUE CAROLINA LIMA DOS SANTOS
ipen.contributor.ipenauthorCAMILA MARINHO GODOI SANTOS
ipen.date.recebimento22-08
ipen.identifier.fi1.7pt_BR
ipen.identifier.fiCiteScore2.5pt_BR
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ipen.type.genreArtigo
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sigepi.autor.atividadeNETO, ALMIR O.:3541:610:Npt_BR
sigepi.autor.atividadeSOUZA, RODRIGO F.B. de:11260:610:Npt_BR
sigepi.autor.atividadeRAMOS, ANDREZZA S.:15158:610:Npt_BR
sigepi.autor.atividadeSILVA, ARACELI J.:15469:610:Npt_BR
sigepi.autor.atividadeNUNES, LIVIA C.:15092:610:Npt_BR
sigepi.autor.atividadeSANTOS, MONIQUE C.L.:14122:610:Npt_BR
sigepi.autor.atividadeGODOI, CAMILA M.:14128:610:Spt_BR
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