Production of methanol on PdCu/ATO in a polymeric electrolyte reactor of the fuel cell type from methane
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Methane
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The search for alternatives for converting methane into value-added products has been of great interest to scientific, technological, and industrial society. An alternative to this could be the use of copper-doped palladium catalysts with different proportions supported on metal oxides, such as Sb2O5.SnO2 (ATO) catalysts. These combinations were employed to convert the methane-to-methanol in mild condition using a fuel cell polymer electrolyte reactor. The catalysts prepared presents Pd, CuO, and Sb2O5.SnO2 phases with a mean particle size of about 9 nm. In activity experiments, the Pd80Cu20/ATO indicated maximum power density and maximum rate reaction for methanol production when compared to other PdCu/ATO materials. The use of ATO as a support favored the production of methanol from methane, while PdCu with high copper content demonstrated the production of more oxidized compounds, such as carbonate and formate.
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GODOI, CAMILA M.; GUTIERREZ, ISABELY M.; GOMES, PAULO V.R.; COELHO, JESSICA F.; ZAMBIAZI, PRISCILLA J.; OTUBO, LARISSA; NETO, ALMIR O.; SOUZA, RODRIGO F.B. de. Production of methanol on PdCu/ATO in a polymeric electrolyte reactor of the fuel cell type from methane. Methane, v. 1, n. 3, p. 218-228, 2022. DOI: 10.3390/methane1030018. Disponível em: http://repositorio.ipen.br/handle/123456789/33449. Acesso em: 30 Dec 2025.
Esta referência é gerada automaticamente de acordo com as normas do estilo IPEN/SP (ABNT NBR 6023) e recomenda-se uma verificação final e ajustes caso necessário.