Conversion of methane into methanol using the [6,6′-(2,2′-bipyridine-6,6′-diyl)bis(1,3,5-triazine-2,4-diamine)](nitrato-O)copper(II) complex in a solid electrolyte reactor fuel cell type

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dc.contributor.authorGARCIA, LUIS M.S.pt_BR
dc.contributor.authorRAJAK, SANILpt_BR
dc.contributor.authorCHAIR, KHAOULApt_BR
dc.contributor.authorGODOY, CAMILA M.pt_BR
dc.contributor.authorSILVA, ARACELI J.pt_BR
dc.contributor.authorGOMES, PAULO V.R.pt_BR
dc.contributor.authorSANCHES, EDGAR A.pt_BR
dc.contributor.authorRAMOS, ANDREZZA S.pt_BR
dc.contributor.authorSOUZA, RODRIGO F.B. dept_BR
dc.contributor.authorDUONG, ADAMpt_BR
dc.contributor.authorNETO, ALMIR O.pt_BR
dc.coverageInternacionalpt_BR
dc.date.accessioned2020-10-22T15:01:38Z
dc.date.available2020-10-22T15:01:38Z
dc.date.issued2020pt_BR
dc.description.abstractThe application of solid electrolyte reactors for methane oxidation to co-generation of power and chemicals could be interesting, mainly with the use of materials that could come from renewable sources and abundant metals, such as the [6,6′- (2, 2′-bipyridine-6, 6′-diyl)bis (1,3,5- triazine-2, 4-diamine)](nitrate-O)copper (II) complex. In this study, we investigated the optimal ratio between this complex and carbon to obtain a stable, conductive, and functional reagent diffusion electrode. The most active Cu-complex compositions were 2.5 and 5% carbon, which were measured with higher values of open circuit and electric current, in addition to the higher methanol production with reaction rates of 1.85 mol L−1 h−1 close to the short circuit potential and 1.65 mol L−1 h−1 close to the open circuit potential, respectively. This activity was attributed to the ability of these compositions to activate water due to better distribution of the Cu complex in the carbon matrix as observed in the rotating ring disk electrode experiments.pt_BR
dc.description.sponsorshipFundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)pt_BR
dc.description.sponsorshipConselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)pt_BR
dc.description.sponsorshipIDFAPESP: 14/09087-4; 14/50279-4; 17/11937-4pt_BR
dc.description.sponsorshipIDCNPq: 300816/2016-2pt_BR
dc.format.extent16003-16009pt_BR
dc.identifier.citationGARCIA, LUIS M.S.; RAJAK, SANIL; CHAIR, KHAOULA; GODOY, CAMILA M.; SILVA, ARACELI J.; GOMES, PAULO V.R.; SANCHES, EDGAR A.; RAMOS, ANDREZZA S.; SOUZA, RODRIGO F.B. de; DUONG, ADAM; NETO, ALMIR O. Conversion of methane into methanol using the [6,6′-(2,2′-bipyridine-6,6′-diyl)bis(1,3,5-triazine-2,4-diamine)](nitrato-O)copper(II) complex in a solid electrolyte reactor fuel cell type. <b>ACS Omega</b>, v. 5, n. 26, p. 16003-16009, 2020. DOI: <a href="https://dx.doi.org/10.1021/acsomega.0c01363">10.1021/acsomega.0c01363</a>. Disponível em: http://repositorio.ipen.br/handle/123456789/31472.
dc.identifier.doi10.1021/acsomega.0c01363pt_BR
dc.identifier.fasciculo26pt_BR
dc.identifier.issn2470-1343pt_BR
dc.identifier.orcid0000-0001-8745-3421pt_BR
dc.identifier.orcidhttps://orcid.org/0000-0002-9287-6071
dc.identifier.percentilfi56.46pt_BR
dc.identifier.percentilfiCiteScore73.00
dc.identifier.urihttp://repositorio.ipen.br/handle/123456789/31472
dc.identifier.vol5pt_BR
dc.relation.ispartofACS Omegapt_BR
dc.rightsopenAccesspt_BR
dc.subjectsolid electrolytes
dc.subjectmethane
dc.subjectfuel cells
dc.subjectcopper complexes
dc.subjectmethanol
dc.subjectoxidation
dc.subjectcarbon
dc.titleConversion of methane into methanol using the [6,6′-(2,2′-bipyridine-6,6′-diyl)bis(1,3,5-triazine-2,4-diamine)](nitrato-O)copper(II) complex in a solid electrolyte reactor fuel cell typept_BR
dc.typeArtigo de periódicopt_BR
dspace.entity.typePublication
ipen.autorCAMILA MARINHO GODOI SANTOS
ipen.autorRODRIGO FERNANDO BRAMBILLA DE SOUZA
ipen.autorALMIR OLIVEIRA NETO
ipen.autorANDREZZA DA SILVA RAMOS
ipen.autorARACELI JARDIM SILVA
ipen.autorLUIS MARCELO GARCIA DA SILVA
ipen.codigoautor14128
ipen.codigoautor11260
ipen.codigoautor3541
ipen.codigoautor15158
ipen.codigoautor15469
ipen.codigoautor15002
ipen.contributor.ipenauthorCAMILA MARINHO GODOI SANTOS
ipen.contributor.ipenauthorRODRIGO FERNANDO BRAMBILLA DE SOUZA
ipen.contributor.ipenauthorALMIR OLIVEIRA NETO
ipen.contributor.ipenauthorANDREZZA DA SILVA RAMOS
ipen.contributor.ipenauthorARACELI JARDIM SILVA
ipen.contributor.ipenauthorLUIS MARCELO GARCIA DA SILVA
ipen.date.recebimento20-10
ipen.identifier.fi3.512pt_BR
ipen.identifier.fiCiteScore3.9
ipen.identifier.ipendoc27246pt_BR
ipen.identifier.iwosWoSpt_BR
ipen.identifier.ods7
ipen.range.fi3.000 - 4.499
ipen.range.percentilfi50.00 - 74.99
ipen.type.genreArtigo
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sigepi.autor.atividadeNETO, ALMIR O.:3541:610:Npt_BR
sigepi.autor.atividadeSOUZA, RODRIGO F.B. de:11260:610:Npt_BR
sigepi.autor.atividadeGODOY, CAMILA M.:14128:610:Npt_BR
sigepi.autor.atividadeGARCIA, LUIS M.S.:15002:610:Spt_BR
sigepi.autor.atividadeRAMOS, ANDREZZA S.:15158:610:N
sigepi.autor.atividadeSILVA, ARACELI J.:15469:610:N
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