Au/TiO2 catalysts prepared by borohydride reduction for preferential CO oxidation at near-ambient temperature
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Catalysis for Sustainable Energy
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Au nanoparticles were prepared in solution
using HAuCl4.3H2O as Au precursor, sodium citrate as
stabilizing agent and sodium borohydride as reducing
agent. The influence of synthesis parameters such as
BH4:Au and Citrate:Au ratios were studied. In a further
step, the stabilized Au nanoparticles were supported on
TiO2 with different Au loadings (wt%). The resulting Au/
TiO2 catalysts were characterized by Energy-dispersive
X-ray spectroscopy, X-ray diffraction and Transmission
Electron Microscopy and tested for the preferential
oxidation of carbon monoxide in hydrogen-rich stream.
Au nanoparticles stabilized in solution were obtained
with sizes in the range of 3-4 nm. After supported on TiO2,
the Au nanoparticles size did not change and the Au/TiO2
catalysts exhibited excellent performance and stability in
the temperature range of 20 - 50 °C.
Como referenciar
LEAL, GEORGIA B.; SILVA, DANIELA C.L. da; WATACABE, BEATRIZ N.; CIOTTI, LIGIA; ANTONIASSI, RODOLFO M.; GIUDICI, REINALDO; LINARDI, MARCELO; VAZ, JORGE M.; SPINACE, ESTEVAM V. Au/TiO2 catalysts prepared by borohydride reduction for preferential CO oxidation at near-ambient temperature. Catalysis for Sustainable Energy, v. 6, n. 1, p. 6-12, 2019. DOI: 10.1515/cse-2019-0002. Disponível em: http://repositorio.ipen.br/handle/123456789/30820. Acesso em: 30 Dec 2025.
Esta referência é gerada automaticamente de acordo com as normas do estilo IPEN/SP (ABNT NBR 6023) e recomenda-se uma verificação final e ajustes caso necessário.