The effect of ethanol concentration on the direct ethanol fuel cell performance and products distribution

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Journal of Power Sources
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ODS 7
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The effect of ethanol concentration on the direct ethanol fuel cell (DEFC) performance and products distribution were studied in situ using a single fuel cell/ATR-FTIR setup. The experiments were performed at 80 C using commercial Pt3Sn/C as anodic catalyst and the concentrations of ethanol solution were varied from 0.1 to 2.0 mol L1 . An increase in power density was observed with the increase of ethanol concentration to 1.0 mol L1 , while the band intensities analysis in the FTIR spectra revealed an increase of acetic acid/acetaldehyde ratio with the increase of ethanol concentration. Also, from FTIR spectra results, it could be concluded that the acetic acid production follow parallel mechanisms; that is, it does not require the presence of acetaldehyde as an intermediate.

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ASSUMPCAO, M.H.M.T.; NANDENHA, J.; BUZZO, G.S.; SILVA, J.C.M.; SPINACE, E.V.; OLIVEIRA NETO, A.; SOUZA, R.F.B. The effect of ethanol concentration on the direct ethanol fuel cell performance and products distribution: a study using a single fuel cell/attenuated total reflectance - fourier transform infrared spectroscopy. Journal of Power Sources, v. 253, p. 392-396, 2014. DOI: 10.1016/j.jpowsour.2013.12.088. Disponível em: http://repositorio.ipen.br/handle/123456789/8546. Acesso em: 30 Dec 2025.
Esta referência é gerada automaticamente de acordo com as normas do estilo IPEN/SP (ABNT NBR 6023) e recomenda-se uma verificação final e ajustes caso necessário.

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