Preparation of PtSn/C-Rh and PtSn/C-CeO2 for ethanol electro-oxidation

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International Journal of Electrochemical Science
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PtSn/CeO2–C electrocatalyst and PtSn/Rh-C were prepared in a two step. In the first step a Carbon Vulcan XC72 + 15%CeO2 and Vulcan XC72 + 15%Rh supports were prepared using a modified polymeric precursor method under controlled synthesis conditions. In the second step PtSn electrocatalyst was prepared by an alcohol-reduction process using ethylene glycol as solvent and reducing agent and supported on Vulcan XC72 + 15%CeO2 and Vulcan XC72 + 15%Rh. The obtained electrocatalysts were characterized by XRD and cyclic voltammetry. The electro-oxidation of ethanol was studied by cyclic voltammetry and chronoamperometry at room temperature. PtSn(50:50)/CeO2–C electrocatalyst showed a significant increase of performance for ethanol oxidation compared to PtSn/C catalyst and others electrocatalysts prepared.

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SOUZA, RODRIGO F.B. de; TUSI, MARCELO M.; BRANDALISE, MICHELE; DIAS, RICARDO R.; LINARDI, MARCELO; SPINACE, ESTEVAM V.; SANTOS, MAURO C. dos; OLIVEIRA NETO, ALMIR. Preparation of PtSn/C-Rh and PtSn/C-CeO2 for ethanol electro-oxidation. International Journal of Electrochemical Science, v. 5, n. 6, p. 895-902, 2010. DOI: 10.1016/S1452-3981(23)15330-2. Disponível em: http://repositorio.ipen.br/handle/123456789/4692. Acesso em: 30 Dec 2025.
Esta referência é gerada automaticamente de acordo com as normas do estilo IPEN/SP (ABNT NBR 6023) e recomenda-se uma verificação final e ajustes caso necessário.

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