New sol-gel method for synthesis of Dy-doped yttrium disilicate phosphor not from TEOS but sodium silicate solution
dc.contributor.author | YAMAGATA, CHIEKO | pt_BR |
dc.contributor.author | MORAIS, VINICIUS R. | pt_BR |
dc.contributor.author | MELLO-CASTANHO, SONIA R.H. | pt_BR |
dc.coverage | Internacional | pt_BR |
dc.creator.evento | PACIFIC RIM CONFERENCE OF CERAMIC SOCIETIES, 13th | pt_BR |
dc.date.accessioned | 2021-01-26T15:23:53Z | |
dc.date.available | 2021-01-26T15:23:53Z | |
dc.date.evento | October 27 - November 1, 2019 | pt_BR |
dc.description.abstract | Yttrium disilicate/pyrosilicate (Y2Si2O7), which occurs naturally as yttrialite, is a mixture of rare earth silicates that displays interesting structural properties because of its high refractoriness (mp = 1775 °C) and stability in oxidizing environments. Yttrium disilicate offers a wide band gap and excellent thermal and chemical stability compared to other well-studied phosphors such as ZnS and CdS. It has been shown to be one of the most efficient host lattices for rare earth ions, which substitute Y3+ ions [1, 2]. Yttrium silicates doped with different metallic ions exhibit attractive luminescent properties for potential applications, such as plasma displays, laser materials and high-energy phosphors [3]. The synthesis methods frequently used to obtain Y2Si2O7 are the conventional solid-state reaction, sol-gel and hydrothermal process. The sol–gel process is based on the polycondensation of hydrolyzed alkoxides or colloidal dispersions, therefore non-substituted and substituted silicon alkoxides are used as source of Si, typically Si(OC2H5)4 (TEOS) or CH3–Si(OC2H5)3 (MTEOS). In the present work, a new method to synthesize Dy-doped yttrium disilicate (Dy0,05Y1,95Si2O7) phosphors is proposed using a combination of sol-gel and coprecipitation techniques. The gel of silica particles were obtained by surfactant-assisted sol-gel process [4], from sodium silicate solution, an unusual precursor of Si. Then yttrium and dysprosium were co-precipitated over these particles. Pure α-phase and β-phase of Y2Si2O7 were obtained after calcining the synthesized precursor at 1100°C and 1400°C respectively (Fig. 1). β-phase showed superior luminescence efficiency (Fig. 2). | pt_BR |
dc.event.sigla | PACRIM | pt_BR |
dc.identifier.citation | YAMAGATA, CHIEKO; MORAIS, VINICIUS R.; MELLO-CASTANHO, SONIA R.H. New sol-gel method for synthesis of Dy-doped yttrium disilicate phosphor not from TEOS but sodium silicate solution. In: PACIFIC RIM CONFERENCE OF CERAMIC SOCIETIES, 13th, October 27 - November 1, 2019, Okinawa, Japan. <b>Abstract...</b> Disponível em: http://200.136.52.105/handle/123456789/31777. | |
dc.identifier.orcid | 0000-0002-0967-0807 | pt_BR |
dc.identifier.orcid | https://orcid.org/0000-0002-0155-9100 | |
dc.identifier.uri | http://200.136.52.105/handle/123456789/31777 | |
dc.local.evento | Okinawa, Japan | pt_BR |
dc.rights | openAccess | pt_BR |
dc.title | New sol-gel method for synthesis of Dy-doped yttrium disilicate phosphor not from TEOS but sodium silicate solution | pt_BR |
dc.type | Resumo de eventos científicos | pt_BR |
dspace.entity.type | Publication | |
ipen.autor | VINICIUS RIBAS DE MORAIS | |
ipen.autor | SONIA REGINA HOMEM DE MELLO CASTANHO | |
ipen.autor | CHIEKO YAMAGATA | |
ipen.codigoautor | 12741 | |
ipen.codigoautor | 1552 | |
ipen.codigoautor | 177 | |
ipen.contributor.ipenauthor | VINICIUS RIBAS DE MORAIS | |
ipen.contributor.ipenauthor | SONIA REGINA HOMEM DE MELLO CASTANHO | |
ipen.contributor.ipenauthor | CHIEKO YAMAGATA | |
ipen.date.recebimento | 21-01 | |
ipen.event.datapadronizada | 2019 | pt_BR |
ipen.identifier.ipendoc | 27548 | pt_BR |
ipen.notas.internas | Abstract | pt_BR |
ipen.type.genre | Resumo | |
relation.isAuthorOfPublication | 9f760f15-bbde-432d-a433-fa230a95f318 | |
relation.isAuthorOfPublication | 421edd64-5958-445c-9f93-1e13aabaa72a | |
relation.isAuthorOfPublication | 9a4bd34a-7406-42f3-8741-5c934840fdc9 | |
relation.isAuthorOfPublication.latestForDiscovery | 9a4bd34a-7406-42f3-8741-5c934840fdc9 | |
sigepi.autor.atividade | MELLO-CASTANHO, SONIA R.H.:1552:720:N | pt_BR |
sigepi.autor.atividade | MORAIS, VINICIUS R.:12741:720:N | pt_BR |
sigepi.autor.atividade | YAMAGATA, CHIEKO:177:720:S | pt_BR |