The influence of imidazolium counterions on the luminescence properties of Cnmim[Eu(tta)4] tetrakis complexes in solid-state and ionic liquid solutions
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Journal of Luminescence
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A series of lanthanide tetrakis complexes Cnmim[Ln(tta)4] where Ln3+: Eu3+ and Gd3+, Cnmim: imidazoliumbased counterions (n from 3 to 8) and tta: thenoyltrifluoroacetonate were synthesized by a one-pot method.
The Cnmim[Ln(tta)4] complexes are thermostable up to 210 ◦C and present an isomorphic-like character for the
complexes with n = 5, 6, and 7. The phosphorescence spectral profile of the Cnmim[Gd(tta)4] complexes showed
intense emission broadbands, in which the barycenters are slightly shifted to energies from the 18,950 to 18,450
cm− 1 range. The Cnmim[Eu(tta)4] complexes in solutions of the corresponding [Cnmim]Br ionic liquids show
similar emission spectral profiles as their corresponding in the solid state, indicating that the coordination
polyhedron does not undergo a significant variation when the chemical environment is changed. Relatively high
values of the intensity parameter Ω2 in both media are presented. The Ω4 values of the complexes in solutions of
ionic liquids are also similar, reinforcing that there are small changes in the polyhedral coordination from the
solid state to the ionic liquid solution. The series presents high intrinsic emission quantum efficiencies,
90% ≥ QEu
Eu ≥ 53%. In addition, theoretical calculations on the intramolecular energy transfer (IET) reveal the
participation of the 7
F0→5
D1 and 7
F1→5
G2 transitions for the IET via S1 while the IET via T1 state is dominated by
the 7
F0→5
D1 and 7
F1→5
D0 transitions. Therefore, due to their high luminescent features, these Eu3+ tetrakis
complexes are potential candidates to be applied as optical markers in the solid-state or even in ionic liquid
solutions.
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PAOLINI, TIAGO B.; ASSUNCAO, ISRAEL P.; COSTA, ISRAEL F.; BLOIS, LUCCA; FELINTO, MARIA C.F.C; MOURA JUNIOR, RONALDO T.; TEOTONIO, ERCULES E.S.; MALTA, OSCAR L.; CARNEIRO NETO, ALBANO N.; BRITO, HERMI F. The influence of imidazolium counterions on the luminescence properties of Cnmim[Eu(tta)4] tetrakis complexes in solid-state and ionic liquid solutions. Journal of Luminescence, v. 263, p. 1-11, 2023. DOI: 10.1016/j.jlumin.2023.120158. Disponível em: http://repositorio.ipen.br/handle/123456789/34254. Acesso em: 30 Dec 2025.
Esta referência é gerada automaticamente de acordo com as normas do estilo IPEN/SP (ABNT NBR 6023) e recomenda-se uma verificação final e ajustes caso necessário.