Glycerol and methanol electro-oxidation at Pt/C-ITO under alkaline condition
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A physical mixture composed by carbon Vulcan
XC 72 and indium tin oxide (ITO) with different ratios
(85 : 15; 50 : 50; 85 : 15) was used as support for platinum
nanoparticles synthesis by borohydride reduction method.
The characterization of this electrocatalyst was performed
by transmission electron microscopy (TEM), X-ray diffraction (XRD), electrochemical techniques cyclic voltammetry (CV), chronoamperometry and performance
test on direct alkaline glycerol/methanol fuel cell (DGFC/
DMFC). According to TEM micrographs, Pt/C-ITO
nanoparticles analysis revealed the presence of large agglomerations of particles. Moreover, it was possible to observe Pt deposition on ITO and also in the carbon surface. The electrochemical studies showed that Pt/C-ITO
(85 : 15) had superior performance for glycerol electro-oxidation, whereas Pt/C-ITO (15 : 85) was the most promising in the methanol oxidation. A comparative study using
direct alkaline fuel cells revealed Pt-C-ITO (15 : 85) electrocatalyst to be the best material for glycerol and methanol oxidation, specifically when being at open circuit potential about 0.95 V, maximum power density of
16 mW cm2 for glycerol and circuit potential 0.95 V, and
maximum power density of approximately 20 mW cm2
for methanol.
Como referenciar
OTTONI, CRISTIANE A.; RAMOS, CARLOS E.D.; SILVA, SIRLANE G. da; SPINACE, ESTEVAN V.; SOUZA, RODRIGO F.B. de; OLIVEIRA NETO, ALMIR. Glycerol and methanol electro-oxidation at Pt/C-ITO under alkaline condition. Electroanalysis, v. 28, p. 1-8, 2016. DOI: 10.1002/elan.201600090. Disponível em: http://repositorio.ipen.br/handle/123456789/26544. Acesso em: 20 Mar 2026.
Esta referência é gerada automaticamente de acordo com as normas do estilo IPEN/SP (ABNT NBR 6023) e recomenda-se uma verificação final e ajustes caso necessário.