Glycerol electrooxidation in alkaline medium using Pd/C, Au/C and PdAu/C electrocatalysts prepared by electron beam irradiation
Carregando...
Data
Data de publicação
Orientador
Título da Revista
ISSN da Revista
Título do Volume
É parte de
É parte de
É parte de
Journal of the Brazilian Chemical Society
ODS
Exportar
Resumo
Pd/C, Au/C and PdAu/C electrocatalysts with different atomic ratios prepared using electron
beam irradiation were tested for glycerol electrooxidation in single alkaline direct glycerol fuel
cell (ADGFC). X-ray diffractograms (XRD) of PdAu/C electrocatalysts showed the presence of
Pd (fcc) and Au (fcc) phases. Cyclic voltammetry (CV) and chronoamperometry showed that
PdAu/C electrocatalyst with Pd:Au atomic ratio of 50:50 demonstrated superior activity for
glycerol electrooxidation, at room temperature. In situ Fourier transform infrared spectroscopy
by attenuated total reflectance (ATR-FTIR) experiments were performed for the electrocatalysts,
identifying oxalate, glycerate ion, 1,3-dihydroxy-2-propanone, glyceraldehyde and glycolate as
products of glycerol electrooxidation. Experiments with single ADGFC were carried out from 50
to 90 °C, using Pd/C electrocatalyst; the best performance was obtained at 80 °C.
Como referenciar
GERALDES, ADRIANA N.; SILVA, DIONISIO F.; SILVA, JULIO C.M.; SOUZA, RODRIGO F.B.; SPINACE, ESTEVAM V.; OLIVEIRA NETO, ALMIR; LINARDI, MARCELO; SANTOS, MAURO C. Glycerol electrooxidation in alkaline medium using Pd/C, Au/C and PdAu/C electrocatalysts prepared by electron beam irradiation. Journal of the Brazilian Chemical Society, v. 25, n. 5, p. 831-840, 2014. DOI: 10.5935/0103-5053.20140044. Disponível em: http://repositorio.ipen.br/handle/123456789/8954. Acesso em: 27 Mar 2026.
Esta referência é gerada automaticamente de acordo com as normas do estilo IPEN/SP (ABNT NBR 6023) e recomenda-se uma verificação final e ajustes caso necessário.