ANDREA NASTRI GRASSO
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Artigo IPEN-doc 14878 Optical properties of metacycline, oxytetracycline and chlortetracycline europium complexes in the presence of hydrogen peroxide2009 - GRASSO, ANDREA N.; TEIXEIRA, LUCIANE dos S.; VIEIRA JUNIOR, NILSON D.; COURROL, LILIA C.Tetracycline possesses a great tendency to form complexes with a number of chemical species, particularly with Eu3+ ions. In this work we investigate the europium optical properties of three tetracyclines europium complexes: Metacycline (MTc), Oxytetracycline (OTc), and Chlortetracycline (CTc), in the presence and absence of hydrogen peroxide (HP). The results show that the emission band of EuOTc have enhancement in the presence of hydrogen peroxide. A calibration curve was shown for this complex with the best molar ratio obtained.Artigo IPEN-doc 16479 Enhancement on the europium emission band of europium chlortetracycline complex in the presence of LDL2010 - TEIXEIRA, LUCIANE dos S.; GRASSO, ANDREA N.; MONTEIRO, ANDREA M.; FIGUEIREDO NETO, A.M.; VIEIRA JUNIOR, NILSON D.; GIDLUND, MAGNUS; COURROL, LILIA C.Low-density lipoprotein (LDL) particles are the major cholesterol-carrying lipoprotein in the human circulation from the liver to peripheral tissues. High levels of LDL-Cholesterol (LDL-C) are known risk factor for the development of coronary artery disease (CAD). The most common approach to determine the LDLC in the clinical laboratory involves the Friedewald formula. However, in certain situations, this approach is inadequate. In this paper we report on the enhancement on the Europium emission band of Europium chlortetracycline complex (CTEu) in the presence of LDL. The emission intensity at 615 nm of the CTEu increases with increasing amounts of LDL. This phenomenon allowed us to propose a method to determine the LDL concentration in a sample composed by an aqueous solution of LDL. With this result we obtained LDL calibration curve, LOD (limit of detection) of 0.49 mg/mL and SD (standard deviation) of 0.003. We observed that CTEu complex provides a wider dynamic concentration-range for LDL determination than that from Eu–tetracycline previously. The averaged emission lifetimes of the CTEu and CTEu with LDL (1.5 mg/mL) complexes were measured as 15 and 46 ls, respectively. Study with some metallic interferents is presented.Artigo IPEN-doc 17846 Investigation of the europium emission spectra of the europium-oxytetracycline complex in the presence of human low-density lipoproteins2011 - TEIXEIRA, LUCIANE dos S.; GRASSO, ANDREA N.; MONTEIRO, ANDREA M.; FIGUEIREDO NETO, ANTONIO M.; VIEIRA JUNIOR, NILSON D.; GIDLUND, MAGNUS; STEFFENS, JULIANA; COURROL, LILIA C.