Methane conversion to higher value‑added product and energy co‑generation using anodes OF PdCu/C in a solid electrolyte reactor
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2021
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Research on Chemical Intermediates
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Resumo
PdxCuy/C catalysts combinations were employed to CH4
partial oxidation in mild
condition using a solid electrolyte reactor—alkaline fuel cell type. The differential
mass spectroscopy on line method was used to monitor the oxidation products
obtained as methanol, dimethyl ether, methyl formate and potassium formate. It was
observed that as the electrical potential of the reactor increases, the generation of
products decreases. The best results for conversion of methane into methanol and
energy co-generation was obtained from Pd90Cu10/
C and Pd50Cu50/
C due to better
H2O
activation effects and adsorption site for CH4
oxidation.
Como referenciar
GODOI, C.M.; SANTOS, M.C.L.; SILVA, A.J.; TAGOMORI, T.L.; RAMOS, A.S.; SOUZA, R.F.B. de; OLIVEIRA NETO, A. Methane conversion to higher value‑added product and energy co‑generation using anodes OF PdCu/C in a solid electrolyte reactor: alkaline fuel cell type monitored by differential mass spectroscopy. Research on Chemical Intermediates, v. 47, n. 2, p. 743-757, 2021. DOI: 10.1007/s11164-020-04296-4. Disponível em: http://repositorio.ipen.br/handle/123456789/31938. Acesso em: 20 Feb 2025.
Esta referência é gerada automaticamente de acordo com as normas do estilo IPEN/SP (ABNT NBR 6023) e recomenda-se uma verificação final e ajustes caso necessário.