Zeolite synthesized from solid Waste for eco-system remediation

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Chemistry
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The present investigation explores the potential of two synthesized zeolites, derived from coal fly ash (CFA; thermoelectric waste) and sugarcane bagasse ash (SCBA; agro-industrial waste), for the selective adsorption of cesium in wastewater. The synthesized zeolites (ZCFA and ZSCBA) were characterized and compared with a commercial zeolite to evaluate their physicochemical properties and effectiveness in removing cesium ions (Cs+) from simulated radioactive wastewater. The results obtained from X-ray diffraction, scanning electron microscopy, and elemental analysis confirmed the successful synthesis of high-purity zeolite from both solid wastes. The impurities present in the ashes impacted the Si/Al ratio and consequently influenced the exchange capacity. After adsorption experiments, neutron activation analysis (NAA) revealed that ZSCBA adsorbed 33.4% of Cs2O by weight, outperforming both ZCFA (26.0%) and commercial zeolite (27.9%). The superior performance of ZSCBA is attributed to its distinct Si/Al ratio and lower levels of impurities, highlighting the impact of these factors on adsorption selectivity. The findings in this study demonstrate the feasibility of valorizing agro-industrial waste for synthesizing zeolites, offering a sustainable approach for managing these residues while producing valuable materials for environmental remediation.

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ARAUJO, MARIANA S.; COSTA-SILVA, DANILO; IZIDORO, JULIANA; FUNGARO, DENISE A.; CASTANHO, SONIA M. Zeolite synthesized from solid Waste for eco-system remediation: selective adsorption in wastewater. Chemistry, v. 7, n. 1, p. 1-14, 2025. DOI: 10.3390/chemistry7010003. Disponível em: https://repositorio.ipen.br/handle/123456789/49637. Acesso em: 30 Apr 2026.
Esta referência é gerada automaticamente de acordo com as normas do estilo IPEN/SP (ABNT NBR 6023) e recomenda-se uma verificação final e ajustes caso necessário.

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